
Tetrahedron p. 15045 - 15066 (1999)
Update date:2022-08-12
Topics:
Craig, Donald
Ford, Mark J.
Gordon, Richard S.
Stones, James A.
White, Andrew J. P.
Williams, David J.
Intramolecular Diels-Alder reactions of cyclohexane-1,2- dicarboxylic anhydride-derived diester-tethered trienes are described. The stereoselectivities of most of the cycloaddition processes studied may be rationalised in terms of an preferred 'inside'-oriented diene giving rise to an endo-transition state.
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Doi:10.1021/ja01315a518
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