Intramolecular Diels-Alder reactions of diester-tethered trienes. Synthesis of medium ring-containing carbocycles and heterocycles

DOI: 10.1016/S0040-4020(99)00960-6

Source and publish data:

Tetrahedron p. 15045 - 15066 (1999)

Update date:2022-08-12

Topics:

Authors:

Craig, Donald

Ford, Mark J.

Gordon, Richard S.

Stones, James A.

White, Andrew J. P.

Williams, David J.

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Article abstract of DOI:10.1016/S0040-4020(99)00960-6

Intramolecular Diels-Alder reactions of cyclohexane-1,2- dicarboxylic anhydride-derived diester-tethered trienes are described. The stereoselectivities of most of the cycloaddition processes studied may be rationalised in terms of an preferred 'inside'-oriented diene giving rise to an endo-transition state.

Full text of DOI:10.1016/S0040-4020(99)00960-6

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