SN1-type mechanism for the carbon-carbon bond cleavage of tetrakis(4-methylphenyl)ethanone cation radical. A laser flash photolysis study

DOI: 10.1016/S0040-4039(00)74731-9

Source and publish data:

Tetrahedron Letters p. 8105 - 8108 (1992)

Update date:2022-08-11

Topics:

Authors:

Akaba, Ryoichi

Kamata, Masaki

Sakuragi, Hirochika

Tokumaru, Katsumi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)74731-9

On the basis of measurements of rate constants for carbon-carbon bond cleavage of tetrakis(4-methylphenyl)ethanone cation radicals generated by pulsed laser excitation with sensitizers in solution, an S_N1-type mechanism for the bond cleavage is proposed.

Full text of DOI:10.1016/S0040-4039(00)74731-9

Products guided by the article

Product name:Methylium, tris(4-methylphenyl)-

Cas No:14039-17-9

R&D Labs maybe for 14039-17-9

Shanghai Yuanding Chem. Sci. & Tech. Co., Ltd.

website:http://www.shydtec.com

Contact:86-21-57721279

Address:Science and Technology Park, Songjiang District, Shanghai, China
HAORUI ENTERPRISES LLC

Contact:(1) 206-3550089

Address:5115 NE 8TH PL, Renton, WA 98059 USA
qingdao goldenchem imp and exp co.,ltd.

Contact:532-55579246

Address:no.62 ,haier road laoshan distirct
Shandong Jiulong Hisince Pharmaceutical Co.,Ltd.

Contact:--

Address:Huadian Pioneer Park, Huadian Township, Qihe County, Dezhou City, Shandong, P.R.China
Shandong General Materials Co.,Ltd（Shandong Aoertong Chemical Co., Ltd）

Contact:86-531-88072280

Address:No. 1825 Hualong Road, Licheng District, Jinan, Shandong, China

Relevant to this article

Scalable Total Syntheses and Structure–Activity Relationships of Haouamines A, B, and Their Derivatives as Stable Formate Salts

Doi:10.1002/chem.202001756
(2020)
Structural, spectroscopic and thermal characterization of 2-tert-butylaminomethylpyridine-6-carboxylic acid methylester and its Fe(III), Co(II), Ni(II), Cu(II), Zn(II) and UO₂(II) complexes

Doi:10.1016/j.saa.2004.06.025
(2005)
Novel tdp1 inhibitors based on adamantane connected with monoterpene moieties via heterocyclic fragments

Doi:10.3390/molecules26113128
(2021)
Synthesis of chiral quaternary fluorinated cyclic sulfamidates via palladium-catalyzed arylation with arylboronic acids

Doi:10.1016/j.tetlet.2019.151280
(2019)
Practical preparation method of polymer-incarcerated (PI) palladium catalysts using Pd(II) salts

Doi:10.1021/ol052310y
(2006)
Radiosynthesis of ¹³N-labeled thalidomide using no-carrier-added [¹³N]NH₃

Doi:10.1002/jlcr.1699
(2010)

Article Doi