SN1-type mechanism for the carbon-carbon bond cleavage of tetrakis(4-methylphenyl)ethanone cation radical. A laser flash photolysis study

DOI: 10.1016/S0040-4039(00)74731-9

Source and publish data:

Tetrahedron Letters p. 8105 - 8108 (1992)

Update date:2022-08-11

Topics:

Authors:

Akaba, Ryoichi

Kamata, Masaki

Sakuragi, Hirochika

Tokumaru, Katsumi

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Article abstract of DOI:10.1016/S0040-4039(00)74731-9

On the basis of measurements of rate constants for carbon-carbon bond cleavage of tetrakis(4-methylphenyl)ethanone cation radicals generated by pulsed laser excitation with sensitizers in solution, an S_N1-type mechanism for the bond cleavage is proposed.

Full text of DOI:10.1016/S0040-4039(00)74731-9

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