Diastereoselective synthesis of optically active C2-substituted spiro[4.5]decanes: Two key intermediates for spirovetivane sesquiterpenes

DOI: 10.1248/cpb.45.459

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 459 - 463 (1997)

Update date:2022-08-11

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Authors:

Takemoto, Yoshiji

Ohra, Taiichi

Yonetoku, Yasuhiro

Iwata, Chuzo

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Article abstract of DOI:10.1248/cpb.45.459

We investigated the stereoselective construction of the C2 stereogenic center of the spiro[4.5]decane skeleton present in the spirovetivanes, spirolaurane, and spiroaxanes, and succeeded in synthesizing 2α- and 2β- substituted 6-spiro[4.5]decanones with d

Full text of DOI:10.1248/cpb.45.459

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