Tetrahedron Letters p. 7571 - 7574 (1998)
Update date:2022-08-30
Topics:
Gaddoni, Lorenzo
Lombardo, Marco
Trombini, Claudio
(3-Bromoalken-1-yl)dialkylboranes, generated by hydroboration of propargyl bromide with dialkylboranes, smoothly rearranges to (E)-allylic boranes which can be trapped with aldehydes. The resulting one-pot three- component sequence represents a route to anti-homoallylic alcohols in fairly good yields.
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