The Reaction of with Triethoxysilane in the Presence of PPh3: a New Method for Synthesis of

DOI: 10.1039/c39950000717

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 717 - 718 (1995)

Update date:2022-08-11

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Authors:

Marciniec, Bogdan

Maciejewski, Hieronim

Gulinski, Jacek

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Article abstract of DOI:10.1039/c39950000717

The reaction of with triethoxysilane in the presence of PPh3 is examined under oxygen-free conditions, permitting isolation of 1 formed by elimination of one acac ligand (as protonated and hydrosilylated product) from the nickel complex with its simultaneous silylation which is followed by C-O bond cleavage in triethoxysilyl ligand via a mechanism involving transfer of an ethyl group to Ni with elimination of pentaethoxyhydrodisiloxane in the excess of triethoxysilane.

Full text of DOI:10.1039/c39950000717

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