Journal of the Chemical Society. Chemical communications p. 137 - 139 (1982)
Update date:2022-08-12
Topics:
Adlington, Robert M.
Aplin, Robin T.
Baldwin, Jack E.
Field, Leslie D.
John, Eeva-M. M.
et al.
δ-(L-α-Amino<1,1,6-17O/18O>-adipyl)-L-cysteinyl-D-valine was converted into isopenicillin N in cell-free extracts of Cephalosporium acremonium with no loss of 17O/18O label as shown by 17O n.m.r. spectroscopy and mass spectrometry; incubation of unlabelled tripeptide in a cell-free system containing 17O/18O-enriched water produced isopenicillin N with no incorporation of 17O/18O.
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