REACTION OF HCo(CO)4 WITH OLEFINS, EFFECT OF Co2(CO)8

DOI: 10.1016/S0022-328X(00)90024-X

Source and publish data:

Journal of Organometallic Chemistry p. 397 - 400 (1981)

Update date:2022-08-17

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Authors:

Ungvary, Ferenc

Marko, Laszlo

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Article abstract of DOI:10.1016/S0022-328X(00)90024-X

Dicobalt octacarbonyl catalyzes the formation of acylcobalt tetracarbonyls and paraffins from olefins and cobalt tetracarbonyl hydride, presumably by generating radical species.The relative reactivities of CO and HCo(CO)4 towards an alkylcobalt carbonyl determine the carbonylation/hydrogenation ratio.

Full text of DOI:10.1016/S0022-328X(00)90024-X

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