
Journal of Organometallic Chemistry p. 397 - 400 (1981)
Update date:2022-08-17
Topics:
Ungvary, Ferenc
Marko, Laszlo
Dicobalt octacarbonyl catalyzes the formation of acylcobalt tetracarbonyls and paraffins from olefins and cobalt tetracarbonyl hydride, presumably by generating radical species.The relative reactivities of CO and HCo(CO)4 towards an alkylcobalt carbonyl determine the carbonylation/hydrogenation ratio.
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