Journal of Organometallic Chemistry p. 269 - 279 (1981)
Update date:2022-08-16
Topics:
Smyslova, E. I.
Perevalova, E. G.
Dyadchenko, V. P.
Grandberg, K. I.
Slovokhotov, Yu. L.
Struchkov, Yu. T.
Organogold(1+) compounds have been synthesized by direct auration of cyclopentadiene, cyanoacetic ester and malonitrile with (Ph3PAu)3O+BF4-.An X-ray structural study (λ Mo, 5062 reflections, R = 0.039) of bis(triphenylphosphinegold)malonitrile has been carried out (monoclinic, a = 12.055(6), b = 14.086(5), c = 20.466(12) Angstroem, β = 90.32(4) deg, space group P21/c, Z = 4).The Au-Au bond length is 2.912(1) Angstroem.
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Doi:10.1007/BF00477370
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