Chemical and Pharmaceutical Bulletin p. 1077 - 1079 (1992)
Update date:2022-08-05
Topics:
Matsunaga
Ishizuka
Marubayashi
Kunieda
The thermal reaction of 3-[(1S)-2-alkoxy-1-apocamphanecarbonyl]-2-oxazolones with dialkyl azodicarboxylates results in exclusive formation of [4 + 2] type cycloadducts with moderate levels of diastereofacial selection, which serve as versatile chiral synthons for a wide variety of 4-alkyl and 4-alkyl-2-oxazolidinones as well as α-amino acids.
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