Journal of the Chemical Society. Chemical communications p. 853 - 854 (1992)
Update date:2022-07-30
Topics:
Srivastava, Anurag
Ma, You-an
Pankayatselvan, Ratnadevi
Dinges, Warren
Nicholas, Kenneth M.
Dioxomolybdenum(VI) complexes including MoO2(dipic)(HMPA) 2a and MoO2(dedtc)2 2b (dipic = 2,6-pyridinedicarboxylate; HMPA = hexamethylphosphoramide; dedtc = N,N-diethyl dithiocarbamate) catalyse the allylic amination of alkenes by phenyl hydroxylamine; the reactions are characterized by a high degree of regioselectivity resulting from double bond migration.
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