
Electrochimica Acta p. 61 - 77 (1971)
Update date:2022-08-11
Topics:
Melendez
Brenet
Kinetic data of a manganese electrode immersed in phosphoric acid solutions at different pH have been established with the aid of polarisation curves obtained by the potentiodynamic method. The passivation phenomena of manganese by the formation of phosphates and the adsorption of oxygen have been obtained on the basis of the data and the theoretical of pH/potential diagrams. It has been established that the rate of spontaneous corrosion is controlled by the diffusion of the Mn(II) phosphate in the solution.
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