Chemical Communications p. 1787 - 1788 (2000)
Update date:2022-08-11
Topics:
Nam
Oh
Mi Hee Lim
Choi
Han
Jhon
An electron-deficient iron porphyrin complex catalyzes the epoxidation of olefins by tert-alkyl hydroperoxides via radical-free oxidation reactions in aprotic solvent; the epoxidation reactions were markedly influenced by reaction temperature and high yields of epoxide products were obtained with retention of stereospecificity at low temperature.
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(1991)