A New Synthetic Route to Aliphatic and Alicyclic Nitriles via Homolytic Desulfurization of α-(Dithiocarbamoylthio) Nitriles

DOI: 10.1246/bcsj.61.2203

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2203 - 2204 (1988)

Update date:2022-08-22

Topics:

Authors:

Yanagawa, Makato

Moriya, Osamu

Watanabe, Yoshihiko

Ueno, Yoshio

Endo, Takeshi

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Article abstract of DOI:10.1246/bcsj.61.2203

Chloroacetonitrile was transformed into aliphatic and alicyclic nitriles through (dimethyldithiocarmoylthio)acetonitrile.The key steps in the synthetic route consisted of mono- and dialkylation via sulfur-stabilized carbanion and homolytic desulfurization using tributyltin hydride.

Full text of DOI:10.1246/bcsj.61.2203

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