Bulletin of the Chemical Society of Japan p. 2203 - 2204 (1988)
Update date:2022-08-22
Topics:
Yanagawa, Makato
Moriya, Osamu
Watanabe, Yoshihiko
Ueno, Yoshio
Endo, Takeshi
Chloroacetonitrile was transformed into aliphatic and alicyclic nitriles through (dimethyldithiocarmoylthio)acetonitrile.The key steps in the synthetic route consisted of mono- and dialkylation via sulfur-stabilized carbanion and homolytic desulfurization using tributyltin hydride.
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