Tetrahedron Letters p. 4357 - 4360 (1993)
Update date:2022-08-11
Topics:
Lester
Gilbin
Inglis
Procopiou
Ross
Watson
The squalestatin 1, has been converted into the 6,7-unsubstituted analogue, 3, via inversion of the alcohol at C7, selective removal of the α,β-unsaturated ester at C6 followed by a Corey-Hopkins deoxygenation of the generated 6R,7S-diol.
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