Chemistry Letters p. 1395 - 1398 (1980)
Update date:2022-08-11
Topics:
Takeuchi, Ken'ichi
Moriyama, Takamasa
Kinoshita, Tomomi
Tachino, Hitoshi
Okamoto, Kunio
1-Adamantyl trifluoromethanesulfonate (1) has been prepared from 1-bromoadamantane and silver trifluoromethanesulfonate in 2,2-dimethylbutane.The trifluoromethanesulfonate (1) abstracts hydride from pentane or hexane to form adamantane, initiates ring-opening polymerization of tetrahydrofuran, and reacts with alkyllithiums to afford 1-alkyladamantanes.
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