Lewis acid-promoted addition of allyl(cyclopentadienyl)iron(II) dicarbonyl to aldehydes: A new aldehyde allylation method

DOI: 10.1016/0040-4039(91)80671-R

Source and publish data:

Tetrahedron Letters p. 3001 - 3004 (1991)

Update date:2022-08-10

Topics:

Authors:

Agoston, Gregory E.

Cabal, Maria P.

Turos, Edward

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Article abstract of DOI:10.1016/0040-4039(91)80671-R

The Lewis acid-promoted addition of allyliron(II) reagent 4 to aldehydes provides zwitterionic iron-olefin complexes 7 as isolable yellow salts. Treatment of the iron complexes with NaI in wet acetone affords homoallylic alcohols 8.

Full text of DOI:10.1016/0040-4039(91)80671-R

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