THE MECHANISM OF RADICAL PRODUCTION FROM THE REACTION OF N,N-DIMETHYLANILINE WITH BENZOYL PEROXIDE

DOI: 10.1016/S0040-4039(00)81681-0

Source and publish data:

Tetrahedron Letters p. 1459 - 1462 (1983)

Update date:2022-08-16

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Authors:

Pryor, William A.

Hendrickson, William H. Jr.

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Article abstract of DOI:10.1016/S0040-4039(00)81681-0

The reaction between dimethylaniline-d₆ and benzoyl peroxyde gives an inverse kinetic isotope effect of 0.93, implying that radicals primarily arise from decomposition of Ph-CO-ON(1+)(Me)2Ph and not from electron transfers.

Full text of DOI:10.1016/S0040-4039(00)81681-0

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