Inorganic Chemistry p. 1815 - 1817 (1968)
Update date:2022-08-31
Topics:
Piacenti
Bianchi
Benedetti
Braca
By reaction of [Ru(CO)3P(C6H5)3]3 with CO, Ru(CO)4P(C6H5)3 has been prepared from which, with halogens (X = Cl, Br, I) or CHCl3, [RuX2(CO)2P(C6H5)3] 2 complexes were obtained. These last compounds could also be formed from [Ru(CO)3P-(C6H5)3]3 and halogens. From the ir spectral data a structure with bridging halogens is suggested for the dimeric compounds [RuX2(CO)2P(C6H5)3] 2. [Os(CO)3P(C6H5)3]3 reacts with CO with displacement of P(C6H5)3 and formation of [Os(CO)4]3.
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(2015)Doi:10.1021/ja900201k
(2009)Doi:10.1111/cbdd.12177
(2013)Doi:10.1021/acs.inorgchem.5b01962
(2015)Doi:10.1021/jacs.7b12198
(2018)Doi:10.1002/anie.201808913
(2018)
