Allylic fluorides via the cleavage of tertiary cyclopropyl silyl ethers with diethylaminosulfur trifluoride

DOI: 10.1039/cc9960001103

Source and publish data:

Chemical Communications p. 1103 - 1104 (1996)

Update date:2022-08-11

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Authors:

Kirihara, Masayuki

Kambayashi, Toshihiro

Momose, Takefumi

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Article abstract of DOI:10.1039/cc9960001103

Treatment of tertiary cyclopropyl silyl ethers with diethylaminosulfur trifluoride (DAST) causes ring opening to give allylic fluorides in moderate to high yields.

Full text of DOI:10.1039/cc9960001103

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