Chemistry Letters p. 867 - 870 (1983)
Update date:2022-08-29
Topics:
Urano, Toshiyuki
Kitamura, Akihide
Sakuragi, Hirochika
Tokumaru, Katsumi
Direct and sensitized photolyses of bis(2-thiophenecarbonyl) (2-TPO) and bis(3-thiophenecarbonyl) peroxide (3-TPO) in benzene afforded biphenyl derived solely from the solvent among the products.The yield of biphenyl depended upon the rate with which the radical intermediates were generated from the peroxides in sufficiently high concentrations to dimerize.
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