Tetrahedron Asymmetry p. 1551 - 1552 (1992)
Update date:2022-08-11
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An asymmetric pinacol-type rearrangement was used in the synthesis of (S)-naproxen. The pinacol-type reaction of a sec-tert vicinal diol provided an α-aryl ketone wich was oxidized with sodium hypochlorite in the presence of methanol to the methyl ester of naproxen.
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Doi:10.1039/c39940001807
(1994)Doi:10.1039/c3ce40883c
(2013)Doi:10.1016/S0040-4020(01)85343-6
(1994)Doi:10.1016/0022-328X(92)86005-O
(1992)Doi:10.1016/j.crci.2012.03.003
(2012)Doi:10.1080/00397919808007045
(1998)
