REACTIONS OF CHROMIUM(II) WITH CHLORO- AND IODOACETONITRILE AND THEIR PENTAAMMINECOBALT(II) COMPLEXES.

Article abstract of DOI:10.1021/ja00316a029

The products and kinetics of the reaction of chromium(II) with XCH//2CN, and (NH**3)//5CoNCCH//2X**3** plus , where X equals I or Cl, have been studied. For X equals I, the free nitrile yields 25% (H//2O)//5CrCH//2CN**2** plus while the cobalt(III) comple