Tetrahedron Letters p. 6589 - 6590 (1997)
Update date:2022-08-11
Topics:
Renard, Pierre-Yves
Six, Yvan
Lallemand, Jean-Yves
New examples of Diels-Alder reactions involving 1,3-disubstituted 1,3-dienylboronates are reported. Various dienophiles were tested. With methyl acrylate as the dienophile, lower reaction temperature, shorter reaction time and better stereocontrol have been reached with the use of a steochiometric amount of Lewis acid EtAlCl2.
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