LXVII. Reactions of some Fe-Ir clusters. Crystal structures of Fe2Ir(μ-H)(μ3-CCHPh)(CO)8(PPh3) and Au2Fe2Ir(μ4-C2Ph)(CO)7(PPh3)3

DOI: 10.1016/0022-328X(91)80102-P

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Journal of Organometallic Chemistry p. 77 - 94 (1991)

Update date:2022-08-29

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Authors:

Bruce, Michael I.

Koutsantonis, George A.

Tiekink, Edward R. T.

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Article abstract of DOI:10.1016/0022-328X(91)80102-P

Isomeric hydrido-vinylidene and -alkyne complexes Fe2Ir(μ-H)(μ₃-X)(CO)8(PPh3) (X = CCHPh, H2CPh) were obtained from Fe2Ir(μ₃-C2Ph)(CO)8(PPh3) and H2 or H^-/H⁺.The X-ray structure of the vinylidene complex is repo

Full text of DOI:10.1016/0022-328X(91)80102-P

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