An efficient phosphorous-containing oxazoline ligand derived from cis-2-amino-3,3-dimethyl-1-indanol: Application to the rhodium-catalyzed enantioselective hydrosilylation of ketones

Article abstract of DOI:10.1016/S0957-4166(97)00424-2

Enantiopure 2-[2-(diphenylphosphino)phenyl]oxazoline, derived from a non-natural amino alcohol, cis-2-amino-3,3-dimethyl-1-indanol, was found to be an efficient ligand for the rhodium-catalyzed enantioselective hydrosilylation of ketones.