Journal of the American Chemical Society p. 3356 - 3362 (1989)
Update date:2022-08-30
Topics:
Stang, Peter J.
Kowalski, Mark H.
Reaction of RC<*>CLi with CH2=C(CH3)Pt(PPh3)2(OTf) results in cis- and trans-(?-alkynyl)(?-vinyl)platinum(II) complexes.The cis isomer is the kinetic product and the trans one the thermodynamic one.X-ray crystal structures of both the cis and trans isomer
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