Stabilization of Carbanions by Polarization of Alkyl Groups on Nonadjacent Atoms

DOI: 10.1021/jo00134a002

Source and publish data:

Journal of Organic Chemistry p. 2504 - 2510 (1982)

Update date:2022-08-11

Topics:

Authors:

Bordwell, Frederick G.

Drucker, George E.

McCollum, Gregory J.

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Article abstract of DOI:10.1021/jo00134a002

Equilibrium acidities in dimethyl sulfoxide solution have been found to increase along the series Me, Et, i-Pr, t-Bu for 9-substituted fluorenes when the alkyl group, R, is separated from the fluorene ring by a CH2, S, or SO2 moiety.This is a reversal of

Full text of DOI:10.1021/jo00134a002

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