Highly regio- and stereoselective reductions of spiroketals

DOI: 10.1016/S0040-4039(00)73980-3

Source and publish data:

Tetrahedron Letters p. 5303 - 5306 (1993)

Update date:2022-08-16

Topics:

Authors:

Oikawa, Hideaki

Oikawa, Masato

Ichihara, Akitami

Kobayashi, Kimiko

Uramoto, Masakazu

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Article abstract of DOI:10.1016/S0040-4039(00)73980-3

Highly regio- and stereoselective reductions of the spiroketals have been achieved by DIBAH and silane-Lewis acid. The key factors of these selectivities were attributed to steric hindrance of α-methyl group at spiroketal and to vicinal ether oxygens for bidentate chelation.

Full text of DOI:10.1016/S0040-4039(00)73980-3

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