FREE RADICAL HALOGENATION OF ALKANES INITIATED BY TRANSITION METAL COMPLEXES

DOI: 10.1016/0022-328X(86)82083-6

Source and publish data:

Journal of Organometallic Chemistry p. 147 - 162 (1986)

Update date:2022-08-24

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Authors:

Davis, Reg

Durrant, Jim L. A.

Rowland, Christopher C.

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Article abstract of DOI:10.1016/0022-328X(86)82083-6

Reaction between halocarbons (particularly CCl4) and hydrocarbons (particularly c-C6H12) in the presence of a range of low valent metal complexes have been investigated.A delaited study of the reaction involving has shown it to proceed by a free radical chain route in which the metal complex acts solely as an initiator.Similar behaviour has been confirmed for . (Re2(CO)10> and show initiation efficiencies comparable with organic peroxides, but other complexes are less efficient.Factors effecting efficiencies have been studied.

Full text of DOI:10.1016/0022-328X(86)82083-6

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