Tetrahedron p. 3565 - 3574 (1988)
Update date:2022-08-17
Topics:
Bihan, J. Y.-Le
Senechal-Tocquer, M.-C.
Senechal. D.
Gentric, D.
Caro, B.
et all.
Phenylpyruvate derivatives can be readily obtained as stable enols and ketones via a new functionalization of arene Cr(CO)3 complexes.An X-Ray structure and theoretical calculations indicate that conjugation stabilizes the enol forms.The complexation of phenylpyruvic acid lowers the conjugation and shifts the keto-enolic equilibrium to the ketonic form.
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