STUDIES IN BIOMIMETIC ALKALOID SYNTHESES-10. THE SYNTHESYS OF A 19-OXOSECODINE AND ITS CYCLIZATION TO MINOVINCINE

DOI: 10.1016/S0040-4020(01)88610-5

Source and publish data:

Tetrahedron p. 3715 - 3718 (1983)

Update date:2022-08-11

Topics:

Authors:

Kuehne, Martin E.

Earley, William G.

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Article abstract of DOI:10.1016/S0040-4020(01)88610-5

The synthesis, isolation and characterization of 19-oxo Δ^20,21 secodine (2) is described.This compound is first example of a stabilized, potentially reactive secodine intermediate in alkaloid synthesis.It cyclized to minovincine (1) in 77 perce

Full text of DOI:10.1016/S0040-4020(01)88610-5

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