A new rearrangement of oxetane-type taxoids

DOI: 10.1016/S0040-4039(00)76801-8

Source and publish data:

Tetrahedron Letters p. 2217 - 2220 (1994)

Update date:2022-08-11

Topics:

Authors:

Appendino, Giovanni

Varese, Marcella

Gariboldi, Pierluigi

Gabetta, Bruno

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Article abstract of DOI:10.1016/S0040-4039(00)76801-8

Treatment of 7-triethylsilyl-14β-hydroxy-10-deacetylbaccatin III (1b) with pyridinium p-toluenesulfonate in refluxing benzene gave the orthoester 3 as a result of O(2) → O(14) benzoate migration, contraction of ring A followed by formation of an ether bri

Full text of DOI:10.1016/S0040-4039(00)76801-8

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