Tetrahedron Letters p. 2217 - 2220 (1994)
Update date:2022-08-11
Topics:
Appendino, Giovanni
Varese, Marcella
Gariboldi, Pierluigi
Gabetta, Bruno
Treatment of 7-triethylsilyl-14β-hydroxy-10-deacetylbaccatin III (1b) with pyridinium p-toluenesulfonate in refluxing benzene gave the orthoester 3 as a result of O(2) → O(14) benzoate migration, contraction of ring A followed by formation of an ether bri
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