Journal of Organic Chemistry p. 5218 - 5224 (1984)
Update date:2022-08-11
Topics:
Chiang, Y.
Chwang, W. K.
Kresge, A. J.
Powell, M. F.
Szilagyi, S.
Rates of reaction with aqueous perchloric acid at 25 deg C have been measured for 1-methyl-cis-cyclooctene, 1-methyl-trans-cyclooctene, and their exo isomer, methylenecyclooctane.The only products formed to any significant extent in each of these reactions are 1-methylcyclooctanol and the cis-cycloalkene, but both the trans- and exo-olefins give these products in initially noneequilibrium proportions:
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