Regio-Controlled Ene-Yne Photochemical Cycloaddition Using Silicon As A Tether

DOI: 10.1016/0040-4039(95)00793-C

Source and publish data:

Tetrahedron Letters p. 4189 - 4192 (1995)

Update date:2022-08-17

Topics:

Authors:

Bradford, Cara L.

Fleming, Steven A.

Ward, Susan C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)00793-C

Substituted cyclobutenes were synthesized by irradiation of silicon tethered ene-ynes.Irradiation of a silicon tethered bisphenylalkyne resulted in cycloaddition and rearrangement to a substituted naphthalene.A diradical intermediate which resembles known DNA cleaving molecules is proposed. - Key Words: 2+2 photocycloaddition, alkoxysilane photochemistry, cyclobutene synthesis

Full text of DOI:10.1016/0040-4039(95)00793-C

Products guided by the article

Product name:diisopropyl(cinnamyloxy)silyl chloride

Cas No:158956-25-3

R&D Labs maybe for 158956-25-3

Zhejiang Tianyu Pharmaceutical Co., Ltd.

Contact:+86-576-84177669, 89189665,89189688,84168770

Address:Jiangkou Development Zone, Huangyan, Taizhou City, Zhejiang
Yancheng Creator Chemical Co., Ltd

Contact:0086-515-88710008 88710068 88710858 88710868

Address:No.21 Renming Road, Longgang Town, Yandu County,Yancheng City
FOSHAN NANHAI ZHONGNAN PHARMACEUTICAL FACTORY

Contact:0086-0757-85609331

Address:XIAHENGTIAN INDUSTRIAL ZONE,SHAYONG VILLAGE,LISHUI TOWN
Weifang Ocean Trading Co., Ltd.

Contact:+86-536-2081155

Address:Room2606, Yuqing Building, 518#, Yuquan Road, High-tech Development Zone, Weifang City, Shandong Province, China
Nanjing Norris Pharm Technology Co., Ltd.

Contact:+86-13901585132

Address:2 Qiande Road, Jiangning sciencepark Hi-Tech Zone, Nanjing, P.R.China

Relevant to this article

Doi:10.1021/ja01287a011
()
Beckmann rearrangement of substituted diaryl ketoximes usng FeCl₃ impregnated montmorillonite K10

Doi:10.1080/00397919708006036
(1997)
Doi:10.1246/bcsj.37.1175
(1964)
Behavior of By-products during Direct-photodegradation Treatment of Trichloroethylene. Effect of Oxygen Concentration on Production of By-products

Doi:10.1246/cl.2003.1046
(2003)
A new cubane-type Ru₄(CO)₁₂(μ₃-Se)₄ tetramer tailored for water photooxidation catalysis

Doi:10.1002/1099-0682(200109)2001:10<2489::AID-EJIC2489>3.0.CO;2-5
(2001)
Spirocyclic and Bicyclic 8-Nitrobenzothiazinones for Tuberculosis with Improved Physicochemical and Pharmacokinetic Properties

Doi:10.1021/acsmedchemlett.8b00634
(2019)

Article Doi