Tetrahedron Letters p. 2571 - 2574 (1995)
Update date:2022-08-25
Topics:
Wang, Jiping
Pomerantz, Martin
A unique halogen exchange reaction between aryl Grignard reagents and aryl halides, which occured during an attempted cross-coupling reaction using non-ligated nickel(II) chloride as a catalyst, has been observed.The halogen exchange takes place between arylmagnesium iodides and aryl bromides but not between arylmagnesium bromides and aryl chlorides.
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Doi:10.1039/c39810001219
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