Chemistry Letters p. 431 - 432 (1994)
Update date:2022-08-29
Topics:
Nakagawa, Shin-ichi
Murata, Satoru
Sakai, Tetsuo
Nomura, Masakatsu
Hydrogenation of biphenyl with the activated hydrogen storage alloy, MmNi3.5Co0.7Al0.8H4 (Mm: La, 30; Ce, 52; Pr, 5; Nd, 13 wtpercent), as a stoichiometric reductant proceeded effectively at 160 deg C for 3 h under nitrogen to give either phenylcyclohexane or bicyclohexyl selectively, according to the ratio of the alloy to biphenyl.
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