Kinetics and mechanism of the oxidation of (α-hydroxyalkyl)chromium complexes by copper(II) and iron(III) ions

DOI: 10.1021/ja00400a040

Source and publish data:

Journal of the American Chemical Society p. 2721 - 2728 (1981)

Update date:2022-08-30

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Authors:

Bakac, Andreja

Espenson, James H.

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Article abstract of DOI:10.1021/ja00400a040

Copper(II) and iron(III) ions react with (α-hydroxyalkyl)chromium(2+) complexes (alkyl = methyl, ethyl, 2-propyl) in water or in aqueous alcohol solutions leading to the cleavage of the chromium-carbon bond. The immediate products are Cr²⁺, the

Full text of DOI:10.1021/ja00400a040

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