Journal of Organic Chemistry p. 4207 - 4211 (1993)
Update date:2022-08-17
Topics:
Minisci, Francesco
Fontana, Francesca
Pianese, Guiseppe
Yan, Yong Ming
Alkyl bromides have been utilized for the first time as radical sources for heteroaromatic substitution.A variety of procedures was revealed to be successful for bromine abstraction: Bu3SnH with AIBN, (Me3Si)3SiH with AIBN, Ph2SiH2, or Et3SiH associated with peroxides (H2O2, t-BuOOH, (t-BuO)2, (t-BuOOCO)2, (PhCOO)2).The importance of the polar effects is discussed.
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