Journal of the Chemical Society. Chemical communications p. 25 - 26 (1995)
Update date:2022-08-10
Topics:
Manz, Berthold
Maas, Gerhard
The 3-alkylidene-4,5-dihydro-3H-1,2,4-diazaphospholes 4, obtained from diphenylmethylene(mesityl)phosphine 3 and silyl diazo ketones 1, undergo thermal extrusion of nitrogen to form alkenyl phosphines 7 and alkylidenephosphiranes 8; the structures of these products have been established by single crystal X-ray structure analyses.
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