Journal of Organic Chemistry p. 641 - 647 (1987)
Update date:2022-08-11
Topics:
Rudolf, Klaus
Robinette, Dan
Koenig, T.
Two short synthetic pathways affording anti-<2,2>(1,6)azulenophane (3) via fluoride-induced 1,8-eliminations from trimethylsilyl-tetraalkylammonium salts are discussed.The structural assignment of the title compound 3 is based on spectral data.Results from flash vacuum pyrolysis experiments suggest that 3 fractures at 620 deg C to generate the corresponding monomer, 1,6-azulylene (1), a highly reactive polyene.
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Doi:10.1016/0022-328X(87)80257-7
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