Journal of Organic Chemistry p. 641 - 647 (1987)
Update date:2022-08-11
Topics:
Rudolf, Klaus
Robinette, Dan
Koenig, T.
Two short synthetic pathways affording anti-<2,2>(1,6)azulenophane (3) via fluoride-induced 1,8-eliminations from trimethylsilyl-tetraalkylammonium salts are discussed.The structural assignment of the title compound 3 is based on spectral data.Results from flash vacuum pyrolysis experiments suggest that 3 fractures at 620 deg C to generate the corresponding monomer, 1,6-azulylene (1), a highly reactive polyene.
View More
Contact:+8613400661290
Address:No 908,Kangwan Rd, Liuyang Economic
Hangzhou Gangjin Chemical Co.,Ltd.(expird)
Contact:+86-571-85109780
Address:707 Zhejiang Minhang Bldg., No.290 Zhongshan North Road, Hangzhou 310003, China
SHIJIAZHUANG CHENSHI IMPORT AND EXPORT CO.,LTD
Contact:+86-311-89871056
Address:RM2017 BUILDING CTIANSHAN GALAXY PLAZA,NO168 CHANGJIANG ROAD,GAOXIN DISTRICT,SHIJIAZHUANG CITY, HEBEI,CHINA
Contact:86-513-84128750/13773795976
Address:No.48.Youyi West Road ,Rudong Development Zone,Jiangsu Province,China
Contact:0512-63006287
Address:no.88.YISHENG Road,etdz-WUJIANG,SUZHOU,CHINA
Doi:10.1016/0022-328X(87)80257-7
(1987)Doi:10.1016/j.apcata.2021.118265
(2021)Doi:10.1016/j.crci.2009.12.001
(2010)Doi:10.1002/hlca.19610440127
(1961)Doi:10.1248/cpb.41.1481
(1993)Doi:10.1016/S0040-4039(03)00619-1
(2003)
