Reaction of Silyl Enol Ethers with N-Chlorosuccinimide: Trapping the Siloxycarbinyl Cation by an Azide Anion

DOI: 10.1039/c39870001727

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1727 - 1728 (1987)

Update date:2022-08-11

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Authors:

Ohkata, Katsuo

Mase, Mikiko

Akiba, Kin-ya

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Article abstract of DOI:10.1039/c39870001727

Reaction of silyl enol ethers (1a-1f) with N-chlorosuccinimide afforded siloxycarbinyl cations which were trapped by nucleophiles (NaN3 and MeOH); subsequebt rearrangement of the azido products (2a,b,d,e-N3) under reflux in decalin led to anilide derivatives (3a,b,d,e).

Full text of DOI:10.1039/c39870001727

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