Synthesis, Molecular Structure and Solution Dynamics of Dimeric Benzamidinates containing a Double Diazaallyl Lithium Bridge. A Rapid Interconversion of ? and ? Bonds

DOI: 10.1039/DT9940003507

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3507 - 3510 (1994)

Update date:2022-08-23

Topics:

Authors:

Eisen, Moris S.

Kapon, Moshe

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9940003507

Dimeric Li reacted with the nitriles 4-XC6H4CN (X = H or Me) in diethyl ether-hexane (1:10) to yield dimeric complexes <4-XC6H4C(NSiMe3)2*Li(NCC6H4X-4)>2 (X = H 1 or Me 2).Complex 2 is dimeric in the solid state with two four-co-ordinated lithium cations bound in N,N'-bidentate ? fashion to one amidine anion (chelating), forming a double diazaallyl lithium bridge, in a monodentate ? fashion to a nitrogen lone pair of a substrate molecule, and monodentrate to a nitrogen lone pair of a second amidine anion.In solution, rapid interconversion of the different lithium-amidine bonds (? to ? and vice versa) was observed by means of the NMR chemical shifts.

Full text of DOI:10.1039/DT9940003507

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Benzamidine hydrochloride

Cas No:1670-14-0

R&D Labs maybe for 1670-14-0

HUNAN CHEMAPI BIOLOGICAL TECHNOLOGY CO.,LTD.

Contact:+86-186-02659358

Address:1004, building 3, Wanke Jinsemaitianyuan, 498 Guitang Road, Yuhua District, Changsha City, Hunan Province, China
Shanghai Profirst Co., Ltd.

Contact:+86-21-38122007

Address:2, Lane 1123, Kangqiao Road, Pudong New Area, Shanghai
Zibo Xiaoguang Chemical Material Co., Ltd

Contact:15954099116

Address:Boshan Development Zone
Sichuan Highlight Fine Chemicals Co., Ltd.

Contact:+86-28-8525 1605

Address:A5-102 Airport base,388 West Airport Huang He Zhong Lu,2 Section
shijiazhuang shuanglian chemical industry co.,ltd

Contact:0311-82190302

Address:Luquan Intersection , Shijiazhuang--Taiyuan Expressway，Shijiazhuang City

Relevant to this article

Wet-chemical synthesis of different bismuth telluride nanoparticles using metal organic precursors-single source vs. dual source approach

Doi:10.1039/c5dt02072g
(2015)
Peroxidase-catalyzed oxidation of 2,4,6-trichlorophenol

Doi:10.1007/s002449900308
(1998)
Doi:10.1039/CT9058700481
(1905)
Doi:10.1021/jo00862a008
(1977)
Azaindole-BODIPYs: Synthesis, fluorescent recognition of hydrogen sulfate anion and biological evaluation

Doi:10.1016/j.saa.2019.01.047
(2019)
N-Allyl-substituted aminomethylene-1,1-bisphosphonates in 1,3-dipolar cycloaddition reaction with aromatic nitrile N-oxides

Doi:10.1007/s11172-017-1881-x
(2017)

Article Doi