Electrochemical Detection of the Cr(CO3)3(MeCN)3+ Intermediate in the One-electron Oxidation of Arene- and Thiophene-chromiumtricarbonyl Complexes

DOI: 10.1039/c39880001264

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1264 - 1266 (1988)

Update date:2022-08-11

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Authors:

Rourke, Frank

Crayston, Joe A.

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Article abstract of DOI:10.1039/c39880001264

Oxidation of LCr(CO)3, (L=C6H6, C6H5Cl, dimethylaniline, thiophene, 3-methylthiophene) in acetonitrile leads to a rapid follow-up reaction in which the intermediate Cr(CO)3(MeCN)3⁺ is detected by cyclic voltammetry.

Full text of DOI:10.1039/c39880001264

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