Journal of Organic Chemistry p. 2011 - 2015 (1988)
Update date:2022-08-29
Topics:
Roussis, Vassilios
Gloer, Katherine B.
Wiemer, David F.
When treated with sodium hydride in dimethoxyethane, some γ-(acyloxy)-β-keto phosphonates react to give 2(3H)-furanones via an unexpected rearrangement which proceeds with carbon-carbon bond formation.Several possible mechanisms for this transformation have been tested through crossover experiments, rearrangement of an isotopically labeled substrate, and synthesis of a model intermediate.Results from these experiments allow elimination of several potential reaction pathways from further consideration and suggest a focus for future studies.
View More
Fusilin chemical science & technology co., ltd.
Contact:532-80698166/86057573, +86-400-669-7885
Address:School of Material Science & Engineering, Shandong Uinversity of Science & Technology, Huangdao Zone, Qindao, Shandong
Changzhou naidechemical Co.Ltd
Contact:+86-519-82589807
Address:NO.25,Houyang street,Jintan,Changzhou City
KangZhiYuan Pharmaceutical Company Limited
Contact:(Sabrina)86-20-85273232
Address:4th floor, building B, Dadi industry zone, Tangxia, Tianhe, Guangzhou, China
Contact:+86 18616952870
Address:Area
Contact:17316303296
Address:240 Amboy Ave
Doi:10.1007/s11164-017-3151-9
(2018)Doi:10.1002/ejic.200901253
(2010)Doi:10.1016/j.bmc.2006.11.016
(2007)Doi:10.1016/0921-4534(95)00566-8
(1995)Doi:10.1016/S1872-2067(10)60116-7
(2010)Doi:10.1016/j.molliq.2014.04.007
(2014)
