Construction of cephem framework via sequential reductive 1,2-elimination-hydride addition in a tributyltin hydride-copper(I) chloride-NMP system: Synthesis of 3-norcephalosporin

DOI: 10.1039/CC9960002705

Source and publish data:

Chemical Communications p. 2705 - 2706 (1996)

Update date:2022-08-17

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Authors:

Tanaka, Hideo

Yamaguchi, Yoshihiko

Sumida, Shin-Ichi

Torii, Sigeru

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Article abstract of DOI:10.1039/CC9960002705

A sequential reductive 1,2-elimination and hydride addition process for 3,4-disubstituted butenoates derived from penicillin is successfully performed with the aid of a combination of tributyltin hydride and copper(I) chloride in N-methyl-2-pyrrolidinone

Full text of DOI:10.1039/CC9960002705

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