Journal of the American Chemical Society p. 4877 - 4882 (1988)
Update date:2022-08-10
Topics:
Dillow, Glen W.
Kebarle, Paul
Measurements of gas phase fluoride transfer equilibria lead to ΔGo and ΔHo for the reaction F- + C6F5X = <*> where the substituents X of the perfluorobenzenes are F, H, CF3, COCH3, CN, and NO2.The relative energy changes are found to lead to an approximately linear correlation with the electron affinities of C6F5X.The gas-phase ΔGo and ΔHo data are used in combination with rate measurements in solution from the literature for a comparison of the reaction coordinates in the gas phase and solution and for determinations of the solvation energy of the transition state occuring in solution.
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