Chemistry of Heterocyclic Compounds p. 500 - 503 (1995)
Update date:2022-08-10
Topics:
Popov, I. I.
In the interaction of benzimidazole-2-thione with 1,2,3-tribromopropane under conditions of interfacial catalysis in an alkaline medium, 2-(2-bromo-2-propenylthio)benzimidazole is formed; debromination of this compound affords 3-methylthiazolo<3,2-a>benzimidazole, which is subsequently converted as aresult of thermolysis to 2-propadienylthio)benzimidazole.
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