Unprecedented Base Effect On the Synthesis of Chiral Phosphinate Esters: A New Route to P-Chiral Phosphine Oxides of High Enantiomeric Purity

DOI: 10.1016/S0957-4166(96)00441-7

Source and publish data:

Tetrahedron Asymmetry p. 3353 - 3356 (1996)

Update date:2022-08-16

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Authors:

Benabra, Abdelhak

Alcudia, Ana

Khiar, Noureddine

Fernandez, Inmaculada

Alcudia, Felipe

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Article abstract of DOI:10.1016/S0957-4166(96)00441-7

The stereochemical outcome of the reaction of chiral secondary alcohols with a phosphinyl chloride was found to be highly dependent on the achiral base used.Thus, the reaction of the readily available sugar derived carbinols, 1 and 2, with methylphenylpho

Full text of DOI:10.1016/S0957-4166(96)00441-7

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