α-Hydrogen Elimination in Some Carbohydrate Triflates

DOI: 10.1016/0040-4039(95)01607-J

Source and publish data:

Tetrahedron Letters p. 7665 - 7668 (1995)

Update date:2022-08-16

Topics:

Authors:

Nemr, Ahmed El

Tsuchiya, Tsutomu

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Article abstract of DOI:10.1016/0040-4039(95)01607-J

In some carbohydrate triflates, treatment with MeLi (or BuLi) in ether caused α-hydrogen elimination initially, then the resulting carbanion is stabilized to give either C-methyl(or butyl)-hydroxy derivatives or unsaturated products.

Full text of DOI:10.1016/0040-4039(95)01607-J

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