Journal of Physical Chemistry p. 13335 - 13340 (1993)
Update date:2022-08-28
Topics:
Tolbert, Laren M.
Harvey, Lilia Cuesta
Lum, Rachel C.
The excited-state proton-transfer (ESPT) reactions of 1-propyl-2-naphthol (PN), 1-(3-hydroxypropyl)-2-naphthol (HPN), and 1-(2,3-dihydroxypropyl)-2-naphthol (DPN) in aqueous methanol solutions have been investigated.The hydroxypropyl and dihydroxypropyl side chains have a pronounced effect on the rate of the proton transfer and on the number of water molecules involved, indicating that proton transfer in alcoholic solvents is more complex than simple models of water clusters can accommodate.Altarnative models in which a side chain facilitates the formation of the requisite geometry for proton transfer are discussed.
View More
Nanjing Fubang Chemical Co.,Ltd
Contact:+86-25-83179199
Address:5F,Tianzheng international plaza,No399 Zhongyang Road ,Nanjing China
HUNAN CHEMAPI BIOLOGICAL TECHNOLOGY CO.,LTD.
Contact:+86-186-02659358
Address:1004, building 3, Wanke Jinsemaitianyuan, 498 Guitang Road, Yuhua District, Changsha City, Hunan Province, China
Huzhou City Linghu Xinwang Chemical Co.,Ltd.
Contact:86-572-3948695/3945236
Address:huzhou
Yingkou Sanzheng Organic Chemical Co. Ltd.
Contact:+86-417-3638818
Address:25 Gengxinli Village, Daqing Road, Yingkou, Liaoning, China
Shanghai Forever Biotech Co., Ltd.
Contact:+86-21-69734790
Address:Room 5017/5019、5022、5024 of Technology Innovation Centre, No.1155, Gongyuan East Rd, QingPu District, Shanghai China.
Doi:10.1021/ic050261f
(2005)Doi:10.1002/aoc.5211
(2019)Doi:10.1021/j100357a028
(1989)Doi:10.1021/jacs.6b10255
(2016)Doi:10.1246/bcsj.54.2374
(1981)Doi:10.1021/bi00643a002
(1977)
